From Chapter 1:
The truth probably is that whoever actually smoked the first pipe, it was Raleigh who brought the practice into common use. It is highly probable, also, that Raleigh was initiated in the art of smoking by Thomas Hariot. This was made clear, I think, by the late Dr. Brushfield in the second of the valuable papers on matters connected with the life and achievements of Sir Walter, which he contributed under the title of "Raleghana" to the "Transactions" of the Devonshire Association. Hariot was sent out by Raleigh for the specific purpose of inquiring into and reporting upon the natural productions of Virginia. He returned in 1586, and in 1588 published the results of his researches in a thin quarto with an extremely long-winded title beginning "A briefe and true report of the new found land of Virginia" and continuing for a further 138 words.

From Chapter 6:
Even children seem to have smoked sometimes in the coffee-houses. Ralph Thoresby, the Leeds antiquary, tells a strange story. He declares that, one evening which he spent with his brother at Garraway's Coffee-house, February 20, 1702, he was surprised to see his brother's "sickly child of three years old fill its pipe of tobacco and smoke it as audfarandly as a man of three score; after that a second and a third pipe without the least concern, as it is said to have done above a year ago." A child of two years of age smoking three pipes in succession is a picture a little difficult to accept as true. As this is the only reference to tobacco in the whole of his "Diary," it is not likely that Thoresby was himself a smoker.